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Description
General description
Dimethyl acetylsuccinate undergoes sulfuric acid catalyzed Pechmann condensation with the corresponding resorcinol derivative to give 7-hydroxycoumarins.
Application
Dimethyl acetylsuccinate has been used in the synthesis of 2-oxofuro[2,3-b]pyrroles and 19-methyl-15-oxa-20-azatricyclo[12.3.3.0(1,14)]icos-18-en-18-carboxylates.
Reactant involved in:
• Cyclization for the synthesis of β-carbolines
• Synthesis of photochromic molecules with improved fatigue resistances and dark form stabilities
• Asymmetric hydrogenation of acylsuccinate followed by lactonization for synthesis of oxotetrahydrofurancarboxylates
• Amidation for synthesis of amino-acid derivatives of dihydropyranocoumarins
Packaging
100, 500 g in glass bottle
- Related Categories Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks More... Quality Level